Issue 28, 2009
From the journal:

Dalton Transactions

Titanocene as a precursor for a cyclopentadienyl-free titanium(iii)–manganese(ii) cluster: a new approach for nano-size materials†

Lucjan B. Jerzykiewicz,a   Józef Utko,a   Marek Duczmalb  and  Piotr Sobota*a  

* Corresponding authors

a Faculty of Chemistry, University of Wrocław, 14. F. Joliot Curie, Wrocław, Poland
E-mail: plas@wchuwr.pl
Fax: +48 71 3282348
Tel: +48 71 3757306

b Faculty of Chemistry, Wrocław University of Technology, 27, Wyspiańskiego, Wrocław, Poland

Abstract

A simple and unique route to access the heterometallic cluster [Mn4Ti4(μ-Cl)2(μ3,η2-L)2(μ,η2-L)10Cl6] (1) with two Mn2Ti2 butterfly core motifs is reported. This method comprises elimination of the Cp ring from Cp2TiCl2 as CpH in the presence of metallic Mn in 2-methoxoethanol (LH) as a proton source. Complex 1 belongs to a group of magnetic clusters, which consists of two weakly interacting M4 subunits.

Graphical abstract: Titanocene as a precursor for a cyclopentadienyl-free titanium(iii)–manganese(ii) cluster: a new approach for nano-size materials

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Article information

DOI
https://doi.org/10.1039/B904830H
Article type
Communication
Submitted
10 Mar 2009
Accepted
08 May 2009
First published
22 May 2009

Dalton Trans., 2009, 5450-5452

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Titanocene as a precursor for a cyclopentadienyl-free titanium(III)–manganese(II) cluster: a new approach for nano-size materials

L. B. Jerzykiewicz, J. Utko, M. Duczmal and P. Sobota, Dalton Trans., 2009, 5450 DOI: 10.1039/B904830H

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